Get Advances in Inorganic Chemistry, Vol. 52 PDF

By AG Sykes

ISBN-10: 0120236524

ISBN-13: 9780120236527

Advances in Inorganic Chemistry offers well timed and informative summaries of the present development in a number of topic parts inside of inorganic chemistry, starting from bioinorganic to good kingdom. This acclaimed serial positive aspects studies written through specialists within the quarter and is an critical connection with complex researchers. each one quantity of Advances in Inorganic Chemistry comprises an index, and every bankruptcy is totally referenced.

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Extra info for Advances in Inorganic Chemistry, Vol. 52

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NMR studies of analogous, but diamagnetic, zinc and cadmium cages indicate that these structures are maintained in solution. No magnetic data are reported. The other octanuclear manganese cage known forms part of a study of heterometallic alkoxides. (103). [MnsSb404(OEt)20] is made from FIG. 14. The structure of [Mns(L3)s(HOPr)4](102). (Shading as Fig. ) HIGH-NUCLEARITY 3d-METAL COMPLEXES 37 reaction of Na(OEt), Sb(OEt)3, and MnC12 in toluene. The oxides are all t~5-bridging, while both ~3- and ~2-ethoxides are present.

Magnetic studies indicate a high-spin ground state of either S -- 10 or S = 11. 18 cm -1 respectively, which would indicate t h a t 31 should be a SMM. c. susceptibility of this cage down to 2 K. Similar cages can be formed by reacting MnC12, Na(OMe), and Hdbm in MeOH, which gives [Na C Mn6(dbm)6(OMe)12] + (32) (94), as shown in Fig. 12, and [Mn C Mn6(dbm)6(OMe)12] (33) (95); the only difference in FIG. 12. The structure of [Na c Mn6(dbm)6(OMe)12]+ (94). ) HIGH-NUCLEARITY 3d-METAL COMPLEXES 33 the synthetic procedure is t h a t Na(BPh4) was added to the reaction, which gave 32.

The presence of the adamantane fragment relates 44 and 45 to the other decanuclear cages, 42 and 43. The magnetic properties of 44 and 45 are less interesting, however, with susceptibility studies indicating a diamagnetic ground state. All the metal centers are Mn(III) in 44 and 45. The Christou group reported the only {Mn11} cage in 1991 (113). It was formed by disrupting the structure of a tetranuclear butterfly cage, [Mn402(O2CMe)7(bpy)2] +, by addition of Me,SiC1. The 42 WINPENNY structure of [MnllOloC12(O2CMe)ll(bpy)2(MeCN)2(H20)2] 2+ 46 (bpy= 2,21-bipyridyl) has considerable aesthetic appeal.

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Advances in Inorganic Chemistry, Vol. 52 by AG Sykes


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